Buffer Recipe Calculator

Calculate the required concentrations and molar amounts of weak acid and conjugate base components using the Henderson-Hasselbalch equation.

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Buffer System properties

Specify acid pKa, target pH, concentration, and volume.

Required Base / Acid Ratio

1.74 ratio

* Ratio of [conjugate base] to [weak acid].

Required Base (A⁻) 63.5 mM (31.8 mmol)
Required Acid (HA) 36.5 mM (18.2 mmol)
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Expert Tip

Buffers work best when target pH is within ±1 unit of the weak acid's pKa. Outside this range, the buffer capacity is rapidly exhausted.

Methodology & Henderson-Hasselbalch

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Henderson-Hasselbalch Equation

The relationship between pH, pKa, and component concentrations is governed by:

pH = pKa + log10([Base] / [Acid])
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Stoichiometric Breakdown

Solving the Henderson-Hasselbalch equation yields:

  • Ratio (R) = 10^(pH - pKa)
  • [Acid] = Total Strength / (R + 1)
  • [Base] = Total Strength * R / (R + 1)

How to Calculate Buffer Recipes (Henderson-Hasselbalch)

Designing buffers requires balancing a weak acid and its conjugate base to achieve a target pH:

1

Identify Buffer pH, pKa and Total Concentration (C)

Find the target pH, the acid dissociation constant (pKa), and total buffer strength.

2

Calculate Ratio (R)

Solve R = 10^(pH - pKa) = [conjugate base] / [weak acid].

3

Determine Individual Concentrations

The weak acid concentration is C / (1 + R). The conjugate base concentration is C × R / (1 + R).

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